张淑华教授

更新时间:2020-12-28 11:12:39点击次数:字号:T|T

基本情况

姓名: 张淑华

性别:

出生年月:19701

籍贯: 湖南邵阳

职称: 教授

联系方式

电话:暂无资料

邮箱:zsh720108@163.com

通讯地址:广东石油化工学院西城校区化学楼216

邮编:525000

个人网站:暂无资料

教育经历

1990.09~1993.06 邵阳学院化学工程化学专业

1999.09~2002.06 广西师范大学化学与化工学院攻读无机化学硕士学位

2005.09~2009.03 南京大学化学与化工学院攻读无机化学博士研究生

工作经历

1993.07-199.08江苏无锡新虹化工有限公司工作;

2002.07-2020.09 桂林理工大学工作,先后任讲师、副研究员、教授等职称,兼任化学与生物工程学院副院长、广西电磁化学功能物质重点实验室副主任等职务;

2012.03-2012.08 Middlesex大学高级访问学者;

2013.10-2014.10 San Jose State大学访问学者;

2020.10-至今,广东石油化工学院化学学院,二级教授,广东石油化工学院高层次人才。

讲授课程

有机波谱分子、无机化学、有机化学、普通化学、化学工程基础、化工制图、化工设备机械基础等本科生课程;单晶结构解析、科技论文阅读与写作、配位化学进展、功能材料等研究生课程。

科研方向

功能材料的设计、合成及性能研究

目前在研科研项目

1. 国家自然科学基金项目:一步法催化合成双手性吡唑酮衍生物及其铜配合物的抗癌活性研究,项目编号;21861014;国家自然科学

2. 基金项目:配体空间位阻调控簇合物的结构及性质研究,项目编号:21161006;

3. 有色金属矿产勘查与资源高效利用协同创新中心团队项目;新型功能材料,项目编号:GXYSXTZX2017-II-3;

4. 企业委托项目:新型稀土材料合作开发;合同编号:20180127;

5. 广东石油化工学院高层次人才引进项目,新型稀土荧光材料的设计,项目编号:520167。

获奖情况

1. “平台+案例”提升化学化工类研究生创新能力培养的研究与实践荣获广西教学成果奖三等奖,主持人:张淑华,证书号:20173030

2. 地方高校化学化工专业产学研协同育人的研究与实践获广西教学成果奖二等奖,参与人:张淑华,证书号:20172008

3. 一目标、二融合、三保障、四举措,八年卓越班工程师教育实验班的探索与实践,广西教学成果奖特等奖,参与人, 证书号:G-T-2019007

4. 弱作用对配合物结构及性质的影响;获广西自然科学三等奖,主持人,证书号:2013-Z-3-003-01

5. 软硬酸碱配位原子(O、N、S)与过渡金属配合物的协同配位能力研究,获广西科学技术进步奖三等奖,参与人,证书号:2006-3-071-03。

2017年以来论著一览

2021

1. San-Tai Wang, Wei-Hui Fang*, Shu-HuaZhang*, Stepwise assembly of multidimensional Al–Pb based coordination polymers, Journal of Solid State Chemistry, 2021, 293, 121804. https://doi.org/10.1016/j.jssc.2020.121804

2. Yezhan Li,   Chengmin Ji,   Lina Li*,   sasa Wang,   Shiguo Han,   Yu Peng,   Shuhua Zhang*  and  Junhua Luo*,  (γ-Methoxy propyl amine)2PbBr4: A Novel Two-dimensional Halide Hybrid Perovskite with Efficient Bluish White-light Emission, Inorganic Chemistry Frontiers, 2021, https://doi.org/10.1039/D0QI01446J

3. Yunlian Yang, Wei Zhong, Ruonan Ma, Chunxin Lu, Zhongquan Shen, Xiaoming Liu, Shuhua Zhang*, Hongming Wang,* Engineering the surface of cuprous oxide via surface coordination for efficient catalysis on aerobic oxidation of benzylic alcohols under ambient conditions, Applied Surface Science, 2021, 543, 148840, https://doi.org/10.1016/j.apsusc. 2020.148840

4. Zhuming Guo, Jing Jin, Zhiyin Xiao,* Naiwen Chen, Xiujuan Jiang, Xiaoming Liu,* Lingfeng Wu, Yi He,* Shuhua Zhang,* Four iron (II) carbonyl complexes containing both pyridyl and halide ligands: their synthesis, characterization, stability and anticancer activity, Appl Organometal Chem. 2021, e6045, DOI: 10.1002/aoc.6045.

5. Qingsong Deng, Yumei Zeng, Jiming Wang, Song Chen, Yu Xiao, Shuhua Zhang*, Heterometallic One-Dimensional Tetranuclear Cu–Na Cluster-Based Polymers: Room Temperature Synthesis, Structures, and Properties, J. Cluster Sci., 2021, 32, 499–505. doi: 10.1007/s10876-020-01809-4

2020

6. Guang-Hui Chen, De-Jing Li, Yan-Ping He*, Shu-Hua Zhang, Fu-Pei Liang*, Jian Zhang*, Self-Assembly of a Ti4(embonate)6 Cage toward Silver, Inorg. Chem., 2020, 59, 20, 14861-14865, https://doi.org/10.1021/acs.inorgchem.0c02308

7. San-Tai Wang, Shu-Hua Zhang, Wei-Hui Fang,* and Jian Zhang*, Stepwise Coordination Assembly Approach toward Aluminum-Lanthanide-based Compounds, Inorg. Chem. 2020, 59, 18, 13760–13766, https://dx.doi.org/10.1021/acs.inorgchem.0c02119。

8. Yan Wang, Yangchun Tan, Nil Kanatha Pandey, Lalit Chudal, Eric Amador, Lipin Sun, Shuhua Zhang, Manbo Zhang, and Wei Chen, FeS2 Loaded Porous SiO2 Ball as a Tweezers Recoverable Heterogeneous Fenton Catalyst with Enhanced Recyclability, Journal of Nanoscience and Nanotechnology, 2020, Vol. 20, 1-9.

9. Yumei Zeng, Haiyang Zhang, Yujie Zhang, Fanghua Ji,* Jinlu Liang,* Shuhua Zhang*,Synthesis, crystal structures, fluorescence, electrochemiluminescent properties, and Hirshfeld surface analysis of four Cu/Mn Schiff‐base complexes, Appl Organometal Chem. 2020, e5712. DOI: 10.1002/aoc.5712

10. Yating Chen, Shaonan Zhang, Yu Xiao*, and Shuhua Zhang*, Synthesis, crystal structures, magnetic and electrochemiluminescent properties of three manganese (II) complexes, ACTA Cryst. C, 2020, C76(3), 236–243, https://doi.org/10.1107/S2053229620001850.

11. Qianjun Deng, Jiming Wang, Guangzhao Li* and Shuhua Zhang*, Synthesis, structure and magnetism of a new ionic pentanuclear iron cluster, Acta Cryst. Section C: Structural Chemistry, 2020, C76, 690-694.

12. WANG Ji-Ming, DENG Qian-Jun,* ZHANG Shu-Hua*, Micro-vial Synthesis, Structure, Magnetic Properties and Hirshfeld Surface Analysis of a Penta-nuclear Fe(III) Cluster, Chinese J. Struct. Chem. 2020, 39(1), 118-125.

13. Shaomei Zhang, Qingsong Deng, Haiyang Zhang, Shuhua Zhang,* Cobalt Cubane Clusters Based on Schiff Base: Synthesis, Characterization, Magnetic Properties and Hirshfeld Surface Analysis, Journal of Cluster Science, 2020, 31(4), 685-691. https://doi.org/10.1007/s10876-019-01675-9.

14. Quanchun Sun, Wei Wang, Chong Zhang, Qiuping Huang*, Shuhua Zhang*, Mononuclear, Dinuclear, and 1-D Chain Structural variations in Zinc(4-fluoro-2-hydroxy-benzoic acid)bipyridine Complexes: Syntheses, Structures, and Luminescence Properties, Journal of Chemical Crystallography, 2020, 50, 308–318, https://doi.org/10.1007/s10870-019-00791-8.

15. Bo Kou, Weichuan Zhang, Chengmin Ji, Zhenyue Wu, Shuhua Zhang,* Xitao Liu,* and Junhua Luo*, Tunable Optical Absorption in Lead-Free Perovskite-Like Hybrids by Iodide Management, Chem. Comm, 2019, 55(94), 14174-14177, https://doi.org/10.1039/ C9CC05365D.

16. Hai-Zhen Li, Shu-Hua Zhang,* Fei Wang,* Facile Syntheses of SOD-type Tetrahedral Tetrazolate Frameworks for Acetylene Storage, Inorg. Chem. Comm. 2020, 113, 107797. 10.1016/j.inoche.2020.107797

17. Guang-Hui Chen, Hai-Zhen Li, Yan-Ping He, Shu-Hua Zhang, Xiaofeng Yi,* Fu-Pei Liang,* Lei Zhang, and Jian Zhang*, Ti4(embonate)6 Based Cage-Cluster Construction in a Stable Metal−Organic Framework for Gas Sorption and Separation, Crystal Growth & Design, 2020, 20(1), 29-32. https://doi.org/10.1021/acs.cgd.9b01297.

18. Yan Zhang, Zhonghang Chen, Xing Liu, Ze Dong, Peixin Zhang, Jun Wang,* Qiang Deng, Zheling Zeng, Shuhua Zhang, and Shuguang Deng, Efficient SO2 Removal Using a Microporous Metal−Organic Framework with Molecular Sieving Effect, Ind. Eng. Chem. Res. 2020, 59(2), 874-882. DOI: 10.1021/acs.iecr.9b06040.

2019

19. Guang-Hui Chen, Yan-Ping He, Shu-Hua Zhang, Fu-Pei Liang*, Lei Zhang and Jian Zhang*, Synthesis and Photoelectric Properties of Metal-organic Zeolites built from TO4 and Organotin, Inorg. Chem. 2019, 58(19), 12521-12525, https://doi.org/10.1021/acs.inorgchem.9b01935

20. Shoucai Wang, Kai Wang, Xiangfei Kong, Shuhua Zhang,* Guangbin Jiang,* and Fanghua Ji,* DMF as Methine Source: Copper-Catalyzed Direct Annulation of Hydrazides to 1,3,4-Oxadiazoles, Advanced Synthesis & Catalysis, 2019, 361, 3986–3990. DOI: 10.1002/adsc.201900395.

21. Qi-Pin Qin,* Zhen-Feng Wang, Ming-Xiong Tan,* Xiao-Ling Huang, Hua-Hong Zou,* Bi-Qun Zou,* Bei-Bei Shi and Shu-Hua Zhang,* Complexes of lanthanides(III) with mixed 2,2′-bipyridyl and 5,7-dibromo-8-quinolinoline chelating ligands as a new class of promising anti-cancer agents, Metallomics, 2019,11, 1005-1015 https://doi.org/10.1039/C9MT00037B.

22. Qi-Pin Qin, Zhen-Feng Wang, Ming-Xiong Tan,⁎ Shu-Long Wang, Bi-Qun Zou⁎, Dong-Mei Luo, Jiao-Lan Qin⁎, Shu-Hua Zhang⁎, Two novel platinum(II) complexes with sorafenib and regorafenib: Synthesis, structural characterization, and evaluation of invitro antitumor activity; Inorg. Chem. Comm. 2019, 104, 27-30. https://doi.org/10.1016/j.inoche.2019.03.031

23. Guang-Hui Chen, Yan-Ping He*, Shu-Hua Zhang*, Jian Zhang, Syntheses, crystal structures and fluorescent properties of two metal-organic frameworks based on pamoic acid, J. Solid State Chem., 270 (2019) 335–338,https://doi.org/10.1016/j.jssc.2018.11.027.

24. Shao-Mei Zhang, Hai-Yang Zhang, Qi-Pin Qin*, Jia-Wei Fei, Shu-Hua Zhang*,Syntheses, crystal structures and biological evaluation of two new Cu(II) and Co(II) complexes based on (E)-2-(((4H-1,2,4-triazol-4-yl)imino)methyl)-6-methoxyphenol, Journal of Inorganic Biochemistry, 2019, 193, 52–59.

25. Zhonghang Chen, Shuhua Zhang,* Shaomei Zhang, Quanchun Sun, Yu Xiao,* Kai Wang*Cd-Based Coordination Polymers from 1D to 3D : Synthesis, Structures, Photoluminescent and Electrochemiluminescent Properties, Chempluschem, 2019, 84, 190-202. DOI: 10.1002/cplu.201800569.

26. Jingwen He, Hairui Pei, Heping Li, Shufen Zhang, ShuhuaZhang,* HaijunTan,* ZhenguangHu, Comparative analysis of phenothiazine and phenoxazine sensitizers for dye-sensitized solar cells, Synthetic Metals, 2019, 247, 228-232.

2018

27. Zhonghang Chen, Yipeng Fan, Jiming Wang, Li Yang, and Shuhua Zhang*, Penta-Nuclear Fe(III) Cluster: Synthesis, Structure, Magnetic, Properties and Hirshfeld Surface Analysis, ChemistrySelect, 2018, 3, 9841-9844, https://doi.org/10.1002/slct.201801968

28. Guang-Hui Chen, Yan-PingHe,* Shu-HuaZhang,* Lei Zhang, A series of zirconium-oxo cluster complexes based on arsenate or phosphonate ligands, Inorg. Chem. Comm., 2018, 97, 125-128, https://doi.org/10.1016/j.inoche.2018.09.013

29. Hao Chen, Zhi-Gang Gu,* Salma Mirza, Shu-Hua Zhang,* and Jian Zhang,* Hollow Cu-TiO2/C Nanospheres Derived from Encapsulated MOF coating for Efficient Photocatalytic Hydrogen Evolution, J. Mater. Chem. A, 2018, 6, 7175-7181. http://dx.doi.org/10.1039/C8TA01034J.

30. Shaonan Zhang, Yao Hua, Zhonghang Chen, Shuhua Zhang,* Hong Hai,* Manganese trinuclear clusters based on schiff base: Synthesis, characterization, magnetic and electrochemiluminescence properties, Inorg. Chim. Acta, 2018, 471, 530-536.

31. Chong Zhang, Yu Xiao*, Yan Qin, Quanchun Sun, Shuhua Zhang*, A novel highly efficient adsorbent {[Co4(L)2(μ3-OH)2(H2O)3(4,4’-bipy)2]·(H2O)2}n: synthesis, crystal structure, magnetic and arsenic (V) absorption capacity, Journal of Solid State Chemistry, 2018, 261, 22–30. DOI: 10.1016/j.jssc.2018.02.012

32. Guang-Hui Chen, Yan-Ping He,* Shu-Hua Zhang,* and Jian Zhang Tuning a layer to a three-dimensional cobalt-tris(4′-carboxybiphenyl)amine framework by introducing potassium ions, Inorg. Chem. Comm., 2018, 90, 65–68, https://doi.org/10.1016/j.inoche.2018.02.006

33. Kai Wang, Zi-Lu Chen, Hua-Hong Zou, Shu-Hua Zhang, Yan Li, Xiu-Qing Zhang, Wei-Yin Sun and Fu-Pei Liang,* Diacylhydrazone-assembled {Ln11} nanoclusters featuring a “double-boats conformation” topology: synthesis, structures and magnetism, Dalton Trans., 2018, 47, 2337-2343.

34. Kai Wang, Shen Tang, Zhao-Bo Hu, Hua-Hong Zou, Xiao-Lu Wang, Yan Li, Shu-Hua Zhang, Zi-Lu Chen and Fu-Pei Liang,* A family of 3d metal clusters based on N–N single bonds bridged quasi-linear trinuclear cores: the Mn analogue displaying single-molecule magnet behavior, RSC Adv., 2018,8, 6218-6224.

35. Qun Tang, Yan-Li Yang, Ning Zhang, Zheng Liu, Shu-Hua Zhang, Fu-Shun Tang, Jia-Yi Hu, Yan-Zhen Zheng, and Fu-Pei Liang*, A Multifunctional Lanthanide Carbonate Cluster Based Metal Organic Framework Exhibits High Proton Transport and Magnetic Entropy Change, Inorg. Chem. 2018, 57, 9020-9027.

2017

36. ZHANG Chong,(张冲) YANG Li,(杨莉) CHEN HAO, (陈浩)  ZHANG Shu-Hua, (张淑华)*, A Novel Dinuclear Copper(II) Complex: Synthesis, Crystal Structure, Properties and Hirshfeld Surface Analysis, Chin. J. Struct. Chem. 2017, 36 (11): 1904-1911. DOI: 10.14102/j.cnki.0254-5861.2011-1611.

37. Chong Zhang, Xuan-Di Ma, Zhong-Hang Chen, Shu-Hua Zhang*, Hong Hai*, Synthesis, Structure and Properties of a Novel Tetranuclear Copper Cluster-Based Polymer with Di-Schiff-Base, J Clust Sci, 2017, 28(6), 3241-3252. doi:10.1007/s10876-017-1295-9. WOS:000414321100017, 19/213

38. Qiu Ping Huang, Shao Nan Zhang, Shu Hua Zhang*, Kai Wang and Yu Xiao*, Solvent and Copper Ion-Induced Synthesis of Pyridyl–Pyrazole-3-One Derivatives: Crystal Structure, Cytotoxicity, Molecules, 2017, 22, 1813, 1-11.

39. Zhehui Weng, Chun Lian Zhang, Hai Yang Zhang, Yanqing Zhou & Shu Hua Zhang*, Syntheses, crystal structures, and spectroscopic properties of two new complexes based on 5-hydroxyisophthalic acid, Inorganic and Nano-Metal Chemistry, 2017, 47(3), 390-395.

40. Hefeng Xu, Xiaodong Fan, Chao Feng & Shuhua Zhang*, Synthesis, crystal structure, and Hirschfeld surface analysis of Ni(II) complex [Ni(H1.5bhbm)2(AcO)]·11H2O containing supra-water network, Inorganic and Nano-Metal Chemistry, 2017, 47(3), 423-426.

41. Shu hua Zhang*, Jiming Wang, Hai-Yang Zhang, Yipeng Fan and Yu Xiao*, Highly efficient electroche miluminescence based on 4-amino-1,2,4-Triazole schiff base two-dimensional Zn/Cd coordination polymers, Dalton Transations, 2017, 46, 410-419. DOI:10.1039/C6DT04059D.

42. Ji-Ming Wang, Chong Zhang, Xiu-Qing Zhang & Shu-Hua Zhang*, Solvothermal synthesis and structure of a cubane cobalt cluster with 3,5-dibromo-2-hydroxybenzaldehyde, Inorganic and Nano-Metal Chemistry, 2017, 47(6), 893-896.


相关成果

专利成果35件,全部转让给有关企业

1.一种单分子磁体[Co4(hmb)4(μ3-OMe)4(MeOH)4]的制备方法,申请人:张淑华、肖瑜、郭晶晶、张义东、王寅光、刘峥,专利号:ZL201110287083.3,发文日期2014.01.08。

2. 3,5-二溴水杨醛缩水合肼双希夫碱的原位合成方法;申请人:张淑华、杨莉,专利号:ZL201210503841.5,发文日期2015.03.05,发文序号:2014110501019990。

3. 荧光材料[ZnNa(ehbd)2N3]2及合成方法,申请人:张淑华、赵儒霞,专利号:ZL201410292786.9,发文日期:2015年9月28日。

4. 一种[Cu2(L3)2]的原位合成方法;申请人:张淑华、黄秋萍、肖瑜、赵儒霞,专利号:ZL201310281414.1,发文序号:2015092800934610,发文日期:2015年10月21日

5. 一种[Cu2(L2)2](C2H3N)2 的原位合成方法; 申请人:张淑华、黄秋萍、肖瑜、张春练, 专利号:ZL201310281430.0发文序号:2015092800970630,发文日期:2015.10.26

6. 3,5-二溴水杨酸吖嗪双希夫碱铜配合物的原位合成方法, 申请人:张淑华,杨莉,肖瑜,张春练;专利号ZL201310210623.7,发文序号:2015120400379160,发文日期:2016.02.05

7. 具抗癌活性的3,5-二溴水杨醛缩2-氨基-2-甲基-1,3-丙二醇希夫碱的合成及应用,申请人:张淑华、李桂、陈林波,专利号:ZL201410829304.9,发文序号:2015110900184320,发文日期:2016.02.26

8. 一种[Mn(L)(AcO)]·(HAc)的原位合成方法;申请人:张淑华、黄秋萍、肖瑜、赵儒霞, 专利号:ZL201310301196.3,发文序号:2016032400394130,发文日期:2016.04.05

9. 荧光材料[CuNa(ehbd)2(dca)(CH3OH)]及合成方法,申请人:张淑华、赵儒霞、周玉洁、张海洋, 专利号:ZL201410418048.4, ZL201410418048.4, 发文序号:2016030300406980,发文日期:2016.04.07

10. [Ni(L)(AcO)(H2O)2](C2H3N)的原位合成方法,申请人:张淑华、黄秋萍、肖瑜、王娓,专利号:ZL201310234398.0发文序号 2016011901299010,发文日期2016.04.11,

11. 5-溴水杨醛缩水合肼双希夫碱的抑菌和抗癌的应用,申请人:张淑华、杨莉, 专利号:ZL201410414182.7,发文序号:2016042400410270,发文日期:2016.05.10.

12. 磁性材料[Co2Na2(hmb)4(N3)2(CH3CN)2]·(CH3CN)2 及合成方法,申请人:张淑华、赵儒霞、周玉洁, 申请专利号:ZL201410292859.4,发文序号:2016050401178920,发文日期:2016.05.13

13. 具抗癌活性的配合物[Zn(H2L4)2]·(H2O)的合成及应用,申请人:张淑华、李桂、陈林波、张海洋。专利号:ZL201510071712.7.发文序号:2016042724040,发文日期:2016年5月19日。

14. 一种配合物[Cu2(L7)(L10)]的原位合成及作为抗癌药物的应用,申请人:肖瑜、黄秋萍、张淑华; 专利号:ZL201410800284.2,发文序号:2016051000352110,发文日期:2016年5月20日。

15. 荧光材料Zn2(hfoac)4(4,4-pybi)2及合成方法,申请人:张淑华、赵儒霞、王娓、陈宁, 专利号:ZL201410418042.7, 发文序号2016050900402850,2016年05月24日。

16. 磁性材料HN(C2H5)3·[Co4Na3(heb)6(N3)6]及合成方法,申请人:张淑华、赵儒霞、周玉洁,专利号:ZL201410292855.6,发文序号:2016052401484740,发文日期:2016年06月21日。

17. 荧光材料Zn(hfoac)2(phen)H2O及合成方法,申请人:周玉洁、赵儒霞、张淑华、王娓; 专利号:ZL201410454852.8,发文序号:2016042500699370,发文日期:2016年06月27日。

18. 荧光材料Zn2(hfoac)4(phen)2及合成方法,申请人:肖瑜、赵儒霞、王娓、陈林波、张淑华, 专利号:ZL201410455028.4,发文序号:2016042500359910,发文日期:2016年06月29日。

19. [Ni(L1)(L2)]·(H2O)3 的原位合成方法;申请人:张淑华、黄秋萍、肖瑜、张春练, 专利号:ZL201310297610.8,发文序号:201607200239580,发文日期:2016年8月8日。

20. 磁性材料[Cu3(N3)6(DMF)2]n及合成方法,申请人:肖瑜、赵儒霞、张淑华,专利号:ZL201410292754.9,发文序号:2016072801446640,发文日期:2016年8月17日。

21. 具抗癌活性的3,5二氯水杨醛缩2-氨基-2-甲基-1,3-丙二醇希夫碱的合成及应用,申请人:张淑华、李桂、陈林波,专利号:ZL201410830039.6,发文序号:2016062900535220,发文日期:2016年8月18日。

22. 磁性材料[Ni2Na2(hmb)4(N3)2(CH3CN)2]·(CH3CN)2及合成方法,申请人:张淑华、赵儒霞、肖瑜, 专利号:ZL201410292900.8,发文序号:20160081501382230,发文日期:2016年8月24日。2017年11月17日。

23. 二(乙氧基水杨醛缩2-氨基-2-甲基-1,3-丙二醇席夫碱)·一乙醇合成及应用,申请人:陈林波、李桂、张淑华,专利号:ZL201410829971.7, 发文日期:2017.02.01。

24. 磁性材料HN(C2H5)3·[Ni4Na3(heb)6(N3)6]及合成方法,申请人:张淑华、赵儒霞、陈林波,申请专利号:201410292880.4,发文序号2017090600392050,发文日期:2017.09.15。

25. 磁性材料[Cu3Na2(ehbd)2(N3)6]n及合成方法,申请人:赵儒霞、张淑华、陈宁,申请专利号:ZL201410292870.0,授权日期:2017年8月28日。

26.  发光材料[Mn(tidc)2]n及合成方法,申请人:张淑华、 张海洋、肖瑜,专利号:ZL201610171182.8, 授权日期:2017年11月07日。

27. 发光材料[Zn(tibc)2]n及合成方法,申请人:张淑华、 张海洋、肖瑜,专利号:ZL201610171237.5, 授权日期:2017年11月6号。

28. 发光材料[Cd (tidc)2]n及合成方法,申请人:张淑华、张海洋、肖瑜,专利号:ZL201610171128.3, 授权日期:2017年11月17号。

29. 发光材料[Mn(tibc)2]n及合成方法,申请人:张淑华、张海洋、肖瑜,专利号:ZL201610171214.4,授权日期:2017年11月17号。

30. 发光材料[Cd(tibc)2]n及合成方法,申请人:张淑华、张海洋、肖瑜,专利号:ZL201610171264.2,授权日期:2017年11月20号。

31. 荧光材料[Cu2Na2(mtyp)2(CH3COO)2(H2O)3]n及合成方法,申请人:甘爱城,张淑华,覃玲,欧燕翠,专利号:ZL201610221790.5, 发文序号:2018052300592670;发文日期:20180529. 32. 具抗癌活性的Cu(mtyp)2(H2O)2的合成及其抗癌活性,申请人:张淑华、张海洋、肖瑜、专利号:ZL201610171185.1,发文日期2018年6月29。

33. 发光材料Cu2(etmp)4及合成方法,申请人:张淑华,杨金武,张海洋,专利号:201610171153.1;发文日期2018年7月2日。

34. 发光材料[Zn(tidc)2]n及合成方法,申请人:肖瑜 张海洋 张淑华,专利号:ZL201610171248.3,发文日期2018年7月2日。

35. 发光材料[Cu(tibc)2]n及合成方法,申请人:张淑华,张海洋,肖瑜,专利号:ZL201610171246.4;发文日期2018年7月2日。


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